Cyclic voltammetry with non-triangular waveforms: Electrochemically irreversible and quasi-reversible systems

Cyclic Voltammetry

Cyclic Voltammetry of Auranofin

The oxidative behavior of Auranofin, 2,3,4,6-tetra-O-acetyl-1-thio-beta-D-glucopyranosato- S(triethylphosphine)gold(I), was investigated by using cyclic voltammetry (CV) in 0.1 M Bu(4)NPF(6)/CH(2)Cl(2) and 0.1 M Bu(4)NPF(4)/CH(2)Cl(2) solutions using Pt working and auxiliary electrodes and a Ag/AgCI reference. CV studies at scan rates from 50-2,000 mV/s and Auranofin concentrations between 1 an...

Transthoracic Ventricular Defibrillation with Triangular and Trapezoidal Waveforms

From 7,200 fibrillation-defibrillation episodes in anesthetized dogs, the effectiveness of 6 classes of unidirectional shocks in reversing ventricular fibrillation of 30-sec duration was determined. The shocks lasted for 1 to 256 msec. Three waveforms (ascending ramp triangular, descending ramp triangular, and trapezoidal) were studied at peak currents of 10 amp and 20 amp. Families of curves o...

Reversible, Irreversible and Optimal -machines

There are two quite diierent possibilities for implementing linear head reduction in-calculus. Two ways which we are going to explain brieey here in the introduction and in details in the body of the paper. The paper itself is concerned with showing an unexpectedly simple relation between these two ways, which we term reversible and irreversible, namely that the latter may be obtained as a natu...

Reversible , Irreversible and Optimal - machinesVincent

There are two quite diierent possibilities for implementing linear head reduction in-calculus. Two ways which we are going to explain brieey here in the introduction and in details in the body of the paper. The paper itself is concerned with showing an unexpectedly simple relation between these two ways, which we term reversible and irreversible, namely that the latter may be obtained as a natu...